if you want the best compatibility with windows office users, you really need Office for mac.
I have tried iWork, and while i really like the applications, it isn't as seamless to edit Office docs... for instance, you can't just open a .doc, work on it and save it as usual... instead, you have to "import it" to convert it to an iWork-friendly format, and then "export" it to convert it back to a .doc. not a big deal to do once or twice, but it would definitely get annoying having to do it ALL the time.
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