You need POP3 access. The only way to get that is to upgrade to a premium account for $19.95 a year. There's no way to do it online - you need to call the number 1-800-494-2962 to have them set it up over the phone. Once you get it, you will be able to plug in the following values for you incoming and outgoing server:
pop3.email.msn.com
smtp.email.msn.com
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